The Baltic Nest Institute (BNI) compiled a uniform dataset based on measurements of monthly discharge and nutrient concentrations of total

N (TN) and total P (TP) for 117 catchments flowing into the Baltic Sea (Mörth et al., 2007 and Smedberg et al., 2006). Time series of 84 catchments span the period 1970–2000, while 33 catchments have data available for the period 1980–2000. Data after the year 2000 are not available. To complement these data, monthly averages of temperature and precipitation of each catchment were obtained from the E-OBS gridded dataset (Haylock et al., 2008, http://eca.knmi.nl). This is a high resolution grid (10 km × 10 km) based on roughly 250 weather stations in Europe (Haylock Selleckchem Venetoclax et al., 2008). Also, fractions of land cover for the year 2000 in the BSDB were retrieved from the Corine Land-use dataset for European catchments. For catchments in Russia, the Global Land Cover dataset was used. These two datasets were merged by the BNI (Mörth et al., 2007). The types of land cover extracted are artificial (urban) area, cultivated area, deciduous forest, coniferous forest, mixed forest, shrubs and herbs, wetlands and water bodies Selleckchem Akt inhibitor (rivers

and lakes). For some years in six catchments located in Estonia, Latvia and Russia (one catchment in the period 1970–1976 and five catchments in the period 1994–2000) only yearly average values for discharge, TN and TP were reported. To restore the monthly seasonality in the data for these catchments and periods, the average monthly deviations from the yearly mean derived from the years with monthly measurements were used to correct the reported yearly average value. Six other catchments were rejected completely for analysis because both monthly and yearly variability was lacking for the period 1980–1990. The rejected catchments were located in the Danish ADP ribosylation factor Straits and the Kattegat. In this study, it was worthwhile to distinguish

between nutrient concentrations and loads (hereafter referred to as TNC, TPC for concentrations and TNL, TPL for loads). In addition, we considered specific loads of nutrients (kg km−2 yr−1) obtained by multiplying concentrations with the discharge and dividing by catchment size. Total loads (kg yr−1) were also considered in this study. With the total load, the net changes in TN and TP exported to the Baltic Sea were calculated. From the total loads, the N:P (mass) ratio was derived which formed another important variable in this study. To analyze potential differences in processes impacting nutrient loads and concentrations by societal change, the BSDB was split up in east and west. All catchments that were located at the eastern side of the historical iron curtain were labelled as ‘east’, the remaining catchments as ‘west’ (Fig. 2 and Fig. 3 show this division).