J Appl Phys 1987,62(4):1278–1283.CrossRef Competing interests The authors declare that they have no competing interests. Authors’ contributions ZS carried out the sample growth, XRD measurements, and data analysis and drafted the manuscript. LW provided the idea, supervised the study, and co-drafted the manuscript. HZ provided the sample design and conducted the photocurrent spectrum tests. WW and HC coordinated the study. All authors read and approved the final manuscript.”
“Background
Possessing low resistivity and excellent compatibility with conventional silicon device processing, transition metal silicide nanowires have been widely studied [1–5]. Compared with silicon nanowires (NWs), fabricating free-standing silicide NWs is more complicated since metal silicides have lots of phases. In terms of methods, the synthesis of free-standing silicide NWs can be divided into four classifications, which are silicidation of silicon nanowires [6–11], Selleck 3Methyladenine delivery of silicon to metal films [12–16],
reactions between transition metal sources and silicon substrates [17–22], and simultaneous metal and silicon delivery [23–25]. Cobalt silicide nanowires have many relatively good characteristics, including low resistivity, good thermal stability, appropriate work function, and compatibility with current processing selleck chemicals of Si devices. There are three main methods for synthesizing CoSi NWs, including reactions of CoCl2 with silicon substrates by chemical vapor deposition (CVD) processes [26–28], cobalt
silicide nanocables grown on Co films [29], and CVD with single-source precursors [30]. In this work, we synthesized cobalt silicide nanowires through CVD processes and changed and studied the effects of several critical processing parameters. Additionally, this website we conducted scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses for identifying the structure and composition of the resultant products and investigating their growth mechanisms. Also, the electrical properties of the nanosilicides were measured and discussed for potential applications. Methods In our study, we synthesized cobalt silicide nanowires by CVD processes using single-crystal Si (100) wafers of native oxide as substrates, anhydrous cobalt chloride powders (97%) as precursors, and Ar gas (99.99%) with H2 gas (15%) as carrier gases. The metal sources were put in the upstream zone where the temperature was 610°C, while the silicon (100) substrates were put in the downstream zone, the temperature range of which was 750°C ~ 900°C. To understand the factors that influence the growth of cobalt silicide nanowires, we conducted learn more experiments with different substrate temperatures, vapor pressures, and gas flow rates. SEM was utilized for the morphology of the nanowires, and TEM analysis was conducted for structure identification and atomic resolution imaging of the nanowires.